Kepala Pemerintahan Luxembourg dikenal dengan . Banyak pemerintahannya sejak Perang Dunia II dibentuk dari hasil koalisi.
| Nama | Lahir - Meninggal | Partai | Perdana Menteri |
|---|---|---|---|
| 1874 - 1973 | Party of the Right (PD) | 1918 - 1925 | |
| 1886 - 1950 | National Independence Party (PNI) | 1925 - 1926 | |
| Joseph Bech | 1887 - 1975 | Party of the Right (PD) | 1926 - 1937 |
| 1885 - 1953 | Party of the Right (PD) | 1937 - 1953 (dalam pengasingan, 1940 - 1944 ) | |
| Tidak ada* | Pendudukan Nazi | 1940 - 1944 | |
| Christian Social People's Party (CSV) | 1944 - 1953 | ||
| Joseph Bech | Christian Social People's Party (CSV) | 1953 - 1958 | |
| 1892 - 1959 | Christian Social People's Party (CSV) | 1958 - 1959 | |
| 1913 - 2002 | Christian Social People's Party (CSV) | 1959 - 1974 | |
| lahir 1928 | Democratic Party (DP) | 1974 - 1979 | |
| Christian Social People's Party (CSV) | 1979 - 1984 | ||
| Jacques Santer | lahir 1937 | Christian Social People's Party (CSV) | 1984 - 1995 |
| Jean-Claude Juncker | lahir 1955 | Christian Social People's Party (CSV) | 1995 - 2013 |
| Xavier Bettel | lahir 1973 | Democratic Party (DP) | 2013 - 2023 |
| Luc Frieden | lahir 1963 | Christian Social People's Party (CSV) | sejak 2023 |
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